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TitleThermal and Photocatalytic Reactions of Methanol and Acetaldehyde on Pt-Modified Brookite TiO2 Nanorods
AuthorPaul A. Pepin*†, Jennifer D. Lee‡ , Christopher B. Murray‡§, and John M. Vohs*†
Affiliation(s)†Department of Chemical and Biomolecular Engineering, ‡Department of Chemistry, and §Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA
PublishedACS Catal., 2018, 8 (12), pp 11834–11846 DOI: 10.1021/acscatal.8b03081
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AbstractThe influence of adding Pt on the catalytic and photocatalytic activity of monodispersed brookite phase TiO2 (B-TiO2) nanorods (NRs) was investigated. Pt was deposited on the NRs by photodeposition in solution, and the Pt-modified NRs were characterized using XPS, STEM, and LEIS. The thermal and photocatalytic activity of the Pt-modified NRs were then evaluated using temperature-programmed desorption (TPD) in ultrahigh vacuum (UHV). ...

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